NAME：METHYL 4,6-O-BENZYLIDENE- α-D-GLUCOPYRANOSIDE

CAS No.：3162-96-7

Molecular Formula:：C₁₄H₁₈O₆

Molecular Weight：282.29

EINECS號(hào)：221-615-2

Quality Standard:

USES:  

• Methyl-4, 6-benzylidene -α -D-glucopyranoside is a commonly used benzylidene protected carbohydrate derivative, usually as an intermediate, widely used in the synthesis of a variety of compounds. 

  The specific application is described as follows:  

•  By synthesizing a deacetyllanatoside glucosyl-modified compound (2-O-benzyl-beta-D-glucopyranoside-deacetyllanatoside and the like) to enhance the antitumous effect of the compound, the potency is improved, the half-life period is prolonged, meanwhile, the modified compound is prepared into a liposome, the hepatic targeting effect of the liposome is improved, and the cardiotoxicity is reduced.
• It is used for the construction of chiral trifluoromethylated quaternary carbon centres
• Synthesis of new C-6 homologues of 1-deoxynojirimycin and 1-deoxy- L –idonojirimycin.
• Use of Propargyl Glycoside for Anomeric Protection
• Synthesis of phenylurethane.
• It is used for  synthesis and antimicrobial studies of pyranmycin.
• Synthesis of several Alkyl Hex-3-enopyranosiduloses.
• This product reacts with dibromomethane in aqueous solution of sodium hydroxide, using tetrabutylammonium bromide as phase transfer agent, can obtain corresponding 2, 3-methylene acetal.  This product protects the 4th and 6th positions
• This product can be oxidated and ring opened by n-bromosuccinimide (NBS), and generate 6-bromo-4-O-benzoyl pyranhexose.